1)(a) prepare down the different laws of thermodynamics and their limitations?
(b) Deduce the first law of thermodynamics for the open system.
2) Enthalpy of the binary liquid system of species 1 and 2 of fixed T and P is represented by equation.
H = 400x_{1}+600x_{2}+x1x_{2} (40x_{1}+20x_{2})
Find out the numerical values for pure species enthalpies H_{1 }and H_{2}.
3) Determine the theoretical horse power needed to produce 400kg/hr of ice at 5^{o}C from water at 15^{o}C. Specific heat of ice and water are 2.1KJ/Kg.C and 4.2K/Kg.C and latent heat of fusion of ice is 320KJ/Kg. Suppose reversed carnot cycle.
4) Design neat and suiatble diagram for absorption refrigeration cycle and describe its working.
5)(a) Describe law of corresponding states in detail.
(b) Deduce a+b in terms of critical properties for Vander walls equation.