1. A 1 m3 tank initially contains air at 300 kPa, 300 K. Air slowly escapes from the tank until the pressure drops to 100 kPa. The air that remains in the tank undergoes a process described by py1.2 5constant. For a control volume enclosing the tank, determine the heat transfer, in kJ. Assume ideal gas behavior with constant specific heats.

2. Nitrogen gas is contained in a rigid 1-m tank, initially at 10 bar, 300 K. Heat transfer to the contents of the tank occurs until the temperature has increased to 400 K. During the process, a pressure-relief valve allows nitrogen to escape, maintaining constant pressure in the tank. Neglecting kinetic and potential energy effects, and using the ideal gas model with constant specific heats evaluated at 350 K, determine the mass of nitrogen that escapes, in kg, and the amount of energy transfer by heat, in kJ.