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Write an equation, clearly showing the stereochemistry of the starting material and the product, for the reaction of (S)-1-bromo-2-methylbutane with sodium iodide in acetone. What is the configuration (R or S) of the product?
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A 3.15- sample of NH4NO3 is introduced intoan evacuated 2.26- L flask and then heated to 245 C. What is the total gas pressure, in atmospheres, in the flask at245 C when the NH4NO3 has completely decomposed?
2KMnO 4 (s) → K 2 MnO 4 (s) + MnO 2 (s) + O 2 (g) If 2.50 L of O 2 (g) is needed at 1.00 atm and 20°C, what mass of KMnO 4 (s) should be decomposed? Assume the decomposition of KMnO 4 (s) goes to completion.
A gas is confined to a cylinder with a moveable piston (to allow the gas to expand or contract) under a pressure of 1 atmosphere. When the temperature of the gas is increased, 850 J of heat is added, and the gas expands, ...
An aqueous solution has a normal boiling point of 102.0°C. What is the freezing point of this solution? For water K b is 0.51°C/ m and K f = 1.86°C/ m.
Suppose 100.0 mL of an aqueous solution containing an unknown monoprotic acid (called HA) is titrated with 0.150 M KOH. The titration requires 47.82 mL of the potassium hydroxide to reach the equivalence point. What is t ...
A student takes 5.0mL of a stock FeSCN2+ solution and dilutes it with deionized water to a volume of 50mL. He then puts the solution in a Spectronic 20 instrument and determines the the % transmittance of the new solutio ...
Diagonal relationship and anomalous behaviour of the each element of the periodic table
The threshold wavelength for the photoelectric effect for silver is 262nm. What is the work function for silver and what is the maximum KE of an emitted electron if the incident light has a wavelength of 212nm?
A 0.0500-mol sample of a nutrient substance is burned in a bomb calorimeter containing 2.00 × 10 2 g H 2 O. If the molar mass of this nutrient substance is 114 g/mol, what is the fuel value (in nutritional Cal) if the t ...
Barium Iodate (Ba(IO3)2) forms an equilibrium with is ions in solution. How does adding additional barium to the solution affect the Ksp of barium iodate. Explain.
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