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Which of the following combinations would be the best to buffer an aqueous solution at a pH of 5.0? H3PO4 and H2PO4- (Ka=7.5e-3) HNO2 and NO2 (Ka=(4.5e-4) CH3CO2H and CH3COO (Ka= 1.8e-5) H2PO4 and HPO4 (Ka=6.2e-8)

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