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What is the pH of a buffer that results when .50 mole of H3PO4 is mixed with .75 mole of NaOH and diluted with water to 1.00 L . The Ka1 is 7.5*10^-3, Ka2=6.2*10^-8 and Ka3*10^-13. Why is 6.2 *10^-8 used?

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