The difference in aqueous nucleophilicity between cl- and, Ask an Expert

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The difference in aqueous nucleophilicity between Cl- and Br- is observed in the product distribution for the Sn2 reaction of 1-butanol (n-butyl alcohol) but not for the Sn1 reaction of 2-methyl-2-propanol (tert-butyl alcohol). Briefly explain this in terms of the Sn rate laws.

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