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problem 1: Suggest a plausible mechanism for the following reaction:

2343_plausible mechanism.jpg

problem 2: Why are electrophilic additions involving H⁺ often mechanistically complex?

problem 3: Addition of H₂ to Cp₂Sc-Me generates Cp₂Sc-H and CH₄. What is the probable mechanism?

problem 4: The following reactions have been shown to proceed through different mechanisms:

Predict products A and B, including stereochemistry, and present a reasonable mechanism for each reaction.

problem 5: For the pairs of complexes given below, predict which one will be more reactive towards oxidative addition of H₂.

a) RhCl(PPh₃)₃ or RhCl(CO)(PPh₃)₂

b) IrCl(CO)(PPh₃)₂ or [PtCl(CO)(PPh₃)₂]⁺

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Chemistry, Academics

Category:- Chemistry
Reference No.:- M93193

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