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Question 1: Calculate or qualitatively correct titration curves for the following acid-base titrations.

(a) 25.0 mL of 0.100 M NaOH with 0.0500 M HCI

(b) 50.0 mL of 0.0500 M HCOOH with 0.100 M NaOH

(c) 50.0 mL of 0.100 M NH3 with 0.100 M HCI

(d) 50.0 mL of 0.0500 M ethylenediamine with 0.100 M HCI

(e) 50.0 mL of 0.0400 M citric acid with 0.120 M NaOH

(f) 50.0 mL of 0.0400 M H3PO4 with 0.120 M NaOH

Question 2:

The protein in a 1.2846-g sample of an oat cereal is determined by the Kjeldahl procedure for organic nitrogen The sample is digested with H2SO4, the resulting solution made. basic with NaOH, and the NH3 distilled into 50.00 mL of 0.09552 M HCl. The excess HCl is then back titrated using 37.84 mL of 0.05992 M NaOH. Given that the protein in grains averages 17.54% w/w N, report the %w/w protein in the sample of cereal.

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