a) prepare notes on the given:
• Nuclear Over hausev Effect (NOE).
• Effect of Hydrogen bonding on chemical shifts.
• Karplus Curve with appropriate illustration.
b) describe the Mc Lafferty rearrangement of various organic molecules.
c) Define the term metastable peak and Nitrogen rule.
a) Describe the photo chemistry of Aromatic compounds and their derivatives.
i) prepare the method of the given reaction:
• Norrish type – I
• Norrish types – II
• Photo Fries rearrangement.
b) Prove that all the (4m+2)π electron system of electro cyclic reactions are thermally dis rotation and photochemically conrotation, by using correlation diagram and FMO methods.
a) prepare the structure elucidation and the synthesis of Quinine.
b) Describe the method of the given rearrangement reaction: