Protonation of the cyanate anion nco- occurs at the n atom, Ask an Expert

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Protonation of the cyanate anion [NCO]- occurs at the N atom and gives a HNC angle of 128 degrees. Protonation of the isomeric fuolminate anion [CNO]- occurs at the C atom and gives an HCN angle of 180 degrees. Discuss why is there a difference in the observed bond angles to hydrogen?

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