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Problem- Calculate the vibrational contribution to the heat capacity and the total heat capacity for the following molecules (harmonic vibrational frequencies given)

a) HCN 3311cm^-1, 2097cm^-1, 712cm^-1, 712cm^-1

b) CCl4 776cm^-1, 776cm^-1, 776cm^-1, 450cm^-1, 314cm^-1, 314cm^-1, 221cm^-1, 221cm^-1, 221cm^-1

I just need a general explanation of it please- Thanks!

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