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Free radical addition reactions:

Those reactions that include the initial attack by a free radical are termed as free radical reactions. Inculcation of hydrogen bromide to alkenes (say, propylene) in the existence of peroxide (radical initiator) follows free radical process. Free radical reactions generally occur in non-polar solvents such as CCl4 high temperature, in existence of light or a free radical generating substance like O2 and peroxides.

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