Calculate the volume of 1M solution of HCl needed for 1 unit shift of the pH of thhe following solutions:
a. 100 mL of 0.1 M solution of weak acid (pKa = 6) and 0.05 M of its sodium salt.
b. 0.005 mole of sodium formiate and 23 g of formic acid dissolved in 100 mL of water. (pKa of formic acid = 3.75)
c. 100 mL of 0.1 M ammonia solution.