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Calculate how many joules are needed to heat 18.2g of tin from 24C° to 37.7C°?

We needed a 50ml of a 0.1 M Tris buffer pH 9.0 then we added 1.0 N HCl or 1.0 N NaOH and water now calculate the theoretical volumes of 1.0 M Tris base?

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