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By analogy to a hydrogen ion buffer, a metal ion buffer tends to maintain a particular metal ion concentration in solution. A mixture of the acid HA and its conjugate base A- maintains [H+] defined by the equation Ka = [A- ][H+] / [HA]. A mixture of CaY2- and Y4 - serves as a Ca2+ buffer governed by the equation 1/K'f = [EDTA][Ca2+] / [CaY2- ]. How many grams of Na2EDTA·2 H2O (FM 372.23) should be mixed with 2.07 g of Ca(NO3)2·2 H2O (FM 200.12) in a 500 mL volumetric flask to give a buffer with pCa2+ = 9.00 at pH 9.00?

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Category:- Chemistry
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