Ask Chemistry Expert

An experiment that illustrates both chemical and electrolyticreduction by the preparation of ammonium vanadium (III) sulfate,(NH4)V(SO4)2.12H20 also known as vanadium alum. Ammonium metavanadate NH4VO3 is reduced by sulfur dioxide to vanadium IV as the vanadyl ion VO2+. This is then reduced by electrolysis ata graphite cathode to vanadium (III).
5g of ammonium metvanadate had 4ml of water added to it. Then20ml of SO2/sulfuric acid solution (1:4 concentrated sulfuric:water) was added which was saturated with SO2. An SO2 bubbler head was attached to the flask. The flask was stoppered and stirred until metavanadate was reduced to vanadylsulfate. The solution was then transferred to a beaker and boiled to expel excess sulfur dioxide.
An electrolytic reduction to vanadium (III) then took place with the vanadyl sulfate solution inside the porous pot and sulfuricacid outside.
Questions are:
(a)What is the coordination geometry about the vanadium ion incrystals of the alum?
(c)Write balanced equations for each reduction step
(d)Assuming an average current of 1.75amps is passed during theelectrolysis, calculate how long it would take to reduce all of theV(IV) in the sample to V(III)?

Chemistry, Academics

  • Category:- Chemistry
  • Reference No.:- M9460529

Have any Question?


Related Questions in Chemistry

Question 1bonding energyi draw an energy level diagram for

Question 1: Bonding Energy i. Draw an energy level diagram for a single Na ion and Cl ion. ii. Explain what is happening to the energy level between these two ions in terms of the Potential Energy. iii. Which process uti ...

Wat is the molarity to the hundredths place of 50 g hpo3

What is the molarity, to the hundredths place, of 5.0 g HPO3 in 300. mL of solution?

Describe how to assign anbspoxidation number from

Describe how to assign a Oxidation number from the text: The oxidation number of an atom in an elemental substance is zero. The oxidation number of a monatomic ion is equal to the ion's charge. Oxidation numbers for comm ...

How many grams of h2so4 must be dissolved into 0709 l of

How many grams of H2SO4 must be dissolved into 0.709 L of solution to generate a concentration of 0.303 M?

What could a source of error be during a titration lab that

What could a source of error be during a titration lab that is not a humans fault?

How many moles of magnesium ion are present in 525g

How many moles of magnesium ion are present in 5.25g Mg 3 (PO 4 ) 2 ?

What is the volume of a solution with a concentration of 12

What is the volume of a solution with a concentration of 1.2 M that contains 12 g of NaOH?

What is the molarity of a solution made by dissolving 200 g

What is the molarity of a solution made by dissolving 20.0 g of CrCl2 in 0.150 L of solution?

What is the mass of naoh present in grams given that a 100

What is the mass of NaOH present in grams, given that a 100. mL solution has a concentration of 0.125 M?

What is the volume of a solution in milliliters that

What is the volume of a solution, in milliliters, that contains 1.5 g LiNO3 and has a concentration of 0.40 M?

  • 4,153,160 Questions Asked
  • 13,132 Experts
  • 2,558,936 Questions Answered

Ask Experts for help!!

Looking for Assignment Help?

Start excelling in your Courses, Get help with Assignment

Write us your full requirement for evaluation and you will receive response within 20 minutes turnaround time.

Ask Now Help with Problems, Get a Best Answer

Why might a bank avoid the use of interest rate swaps even

Why might a bank avoid the use of interest rate swaps, even when the institution is exposed to significant interest rate

Describe the difference between zero coupon bonds and

Describe the difference between zero coupon bonds and coupon bonds. Under what conditions will a coupon bond sell at a p

Compute the present value of an annuity of 880 per year

Compute the present value of an annuity of $ 880 per year for 16 years, given a discount rate of 6 percent per annum. As

Compute the present value of an 1150 payment made in ten

Compute the present value of an $1,150 payment made in ten years when the discount rate is 12 percent. (Do not round int

Compute the present value of an annuity of 699 per year

Compute the present value of an annuity of $ 699 per year for 19 years, given a discount rate of 6 percent per annum. As