Assuming complete dissociation of the solute, how many grams of \rm KNO_3 must be added to 275 \rm mL of water to produce a solution that freezes at -14.5 ^\circ {\rm C}? The freezing point for pure water is 0.0 ^\circ {\rm C} and K_f is equal to 1.86 ^\circ {\rm C}/m.