A substance as elementary and well known as argon still, Ask an Expert

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A substance as elementary and well known as argon still receives research attention. Stewart and Jacobsen have published a review of thermodynamic properties of argon that included the following 300 K isotherm.

p/MPa	0.4000	0.5000	0.6000	0.8000	1.000
V_m/(dm³mol^-1)	6.2208	4.9736	4.1423	3.1031	2.4795
p/MPa	1.500	2.000	2.500	3.000	4.000
V_m/(dm³mol^-1)	1.6483	1.2328	0.98357	0.81746	0.60998

(a) Compute the second virial coefficient, B, at this temperature.

(b) Use non-linear curve-fitting software to compute the third virial coefficient, C, at this temperature.

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