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1. In the reaction of potassium permanganate and iron salt in acidic medium, how many moles of manganese reacted with iron?

2 moles of Mn with 1 mole of Fe

1 mole of Mn with 5 moles of Fe

1 mole of Mn reacts with 1 mole of Fe

5 moles of Mn reacts with 1 mole

2 Which of the following is not correct about potassium permanganate when used in titrimetric analysis?

It is a primary standard

It acts in acidic medium

It acts in basic medium

It requires the use of an external indicator

3 When starch is used in iodiometric titration, the colour changes from -----------

Red to blue at the end point

Blue black to colourless at the end point

Colourless to orange at the end point

Light yellow to brown at the end point

4 What is the oxidation of chromium in potassium dichromate?

+1

+4

+6

+7

5 Which the following is not a primary standard

Potassium permanganate

Oxalic acid

Ammonium iron (II)sulphate

Sodium oxalate

6 A standard solution is a ----------------.

Dilute solution

Solution of known concentration

Concentrated solution

Measured solution

7 When a substance is not available in a pure form, its solution can be standardized by ---------------.

Re- crystallizing the substance and diluting it

Titrating againt a substance of unknown concntration

Titrating against a substance of known concentration

Preparing a new solution of the substance

8 A pure substance could be described as -----------.

A white crystalline sample

A sample with little impurities

A sample which maintains its physical appearance with time

A sample which does not change its chemical composition during storage

9 On heating a substance prior to weighing, it is placed --------------.

On the laboratory desk

In water

In a fume hood

In a dessicator

10 Heating sodium bicarbonate before its use as a standard expels

Carbon dioxide only

water and carbon dioxide

Water only

Impurities

11 3.47g sodium carbonate was dissolved in a 250millilitre standard flask. What is the concentration of the resulting solution

0.13M

0.52M

0.66M

0.40M

12 One of the following is not a proper way of preparing 0.025M solution from 1.00M stock solution.

2.5 mL of stock solution is diluted to 100mL

25 mL of stock solution is made up to 1000mL

12.5 mL of the stock solution is made up to 500mL

12.5 mL of the stock solution is made up to 750mL

13 All the following apparatus are needed for the preparation of a solution of hydrochloric acid, HCl, from the concentrated solution EXCEPT --------------.

Measuring cylinder

Burette

Crucible

Volumetric flask

14 If 15cm 3 of 10.25M HCl solution is made up to volume in a 500 Ml volumetric flask, what will be its new concentration?

0.306M

3.06M

5.13M

0.52M

15 In the preparation of a solution, it is advisable to shake the mixture well. This is necessary to ----------------.

Ensure that the solution precipitates out very well

Induce air bubbles in the solution

Produce a homogenous solution

Facilitate use of lesser volume of water

16 To dilute an acid with water, acids are added to water and not water to acid because -----------------.

Acids are more vicourse than water

Water is weaker than acid

Dissolution of acid in water is exothermic which could be explosive

Acids will not dissolve in water if done wrongly

17 During standardization of HCl with sodium carbonate titration, the pipette is rinsed with distilled water and thereafter with ------------.

the HCl solutin

The methyl orange indicator

the Na 2 CO 3 solution

More water

18 In a standardization titration involving hydrochloric acid and sodium carbonate, a student recoirded the following results for the volume of hydrochloric acid used against 10.00mL of the sodium carbonate solution : 15.60; 14.50; 14.70 aqnd 14.20. What is

14.60mL

14.75mL

14.47mL

14.00mL

19 In a standardization titration involving hydrochloric acid and sodium carbonate, a student recoirded the following results for the volume of hydrochloric acid used against 10.00mL of the sodium carbonate solution : 15.60; 14.50; 14.70 aqnd 14.20. If the c

1.02 Ml

1.03mL

1.07mL

1.04M

20 In titration, the experimentally determined stoichiometric point of the titration is referred to as--------------.

Flash point

Critical point

Equivalence point

stop point

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