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1. How many grams of dry NH4Cl need to be added to 2.40 L of a 0.200 M solution of ammonia, NH3, to prepare buffer solution that has a pH of 8.83? Kb for ammonia is 1.8×10-5.

2. A beaker with 115 mL of an acetic acid buffer with a pH of 5.000 is sitting on a benchtop. The total molarity of acid and conjugate base in this buffer is 0.100 M

A student adds 4.20 mL of a 0.490 HCl solution to the beaker. How much will the pH change? The pKa of acetic acid is 4.740.

3. Calculate the molar solubility of SrF2 in the following substances.

1.5×10-2 M Sr(NO3)2

1.3×10-2 M NaF

4. There is a solution that is 3.5×10-2 M in HCN (Ka=4.9×10-10) and 1.0×10-2 M in NaCN. Calculate the percent dissociation of HCN in this solution.

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