Answer the following problems.

problem 1) describe the Job’s method for the determination of stability constant of a complex.

problem 2) What are the factors which affect the stability of a complex?

problem 3) describe the Jahn-Teller effect on geometry of octahedral complexes with suitable exs.

problem 4) Describe the magnetic and geometry nature of outer and inner orbital complexes based on VBT.

problem 5) Anhydrous CuSO4is colourless where as hydrated CuSO4 is blue. Describe in detail.

problem 6) prepare a detail note on the following:

(i) Spectrochemical series,

(ii) crystal field stabilization energy (CFSE),

(iii) Chelate effect.

problem 7) How do you describe ability and inertness of coordination compounds based on VBT and CFT?

problem 8) describe the structure and bonding of metal nitrosyls with appropriate exs.

problem 9) Describe SN’CB mechanism with appropriate ex.